PC isn't a great choice for any engine pieces. Heat retention is a real concern...so is heat, like around the exhaust port. The outer covers are sure to get scratched & nicked along the way. PC is NOT refinisher-friendly. And when it comes to touch-ups...fuhggeddaboudit!!
Rod length has no bearing on stroke length. It does have to be matched to piston compression height, i.e. the distance from the wrist pin to the piston crown, as measured at the top of the compression ring land. The 6v motors had shorter rod length; using a 12v (long rod) piston with a 6v (short rod) crank assembly would leave the piston way down in the bore (negative deck height), leaving the combustion chamber without a squish band and the motor with pathetically low compression. Using a 6v piston with a 12v crank assembly would leave the piston above the deck at TDC...no need to worry about compression ratio, it'd hit the head.
FYI, rod/stroke ratio affects the shape of an engines power band. The longer the rod, the higher (numerically) the R/S ratio and the higher the rpm limits.
Any of the 72cc heads will have larger ports & valves, definitely better breathing than a 49cc head. The 72cc heads have larger combustion chambers than the 49cc flavor. Thus, the piston type should be matched, to maintain CR. Again, of the possible mismatches, one will give low compression, the other mechanical interference.